Silanes are bifunctional molecules that act as adhesion promoters, crosslinkers and moisture scavengers in many different applications.
The properties and effects of silanes are defined by their molecular structure:
Y-(CH2)n-Si(OX)3, where:
Y = organofunctional group
OX = silicon-functional group
n = 0 or 3
The organofunctional group Y links with the polymer. This group must be chosen carefully to ensure maximum compatibility with the resin. The silicon-functional groups OX, usually alkoxy groups, must be hydrolyzed to the silanol (Si-OH) first before they can bond to the substrate or crosslink.
In general, ethoxy silanes will hydrolyze at a slower rate than their methoxy equivalents.
Choosing the right silane for your silane application by using the guide below or contacting our experts. The organic functional groups listed below can be used with Thermoplastic resins, Thermosetting resins, or Elastomeric applications:
polymer | Amino | Epoxy | Sulfur | Mercapto | Methacryloxy | Vinyl |
Acrylic | ☆ | ☆ |
| △ | △ |
|
Acrylic latex | # | △ |
|
| ☆ | ☆ |
Butyl |
| △ | △ | △ | ☆ |
|
Cellulosics | △ |
|
|
|
| # |
Epoxy | ☆ | △ |
| △ |
|
|
Furan | ☆ | △ |
|
|
|
|
Melamine | ☆ | △ |
|
|
|
|
Neoprene |
|
|
| ☆ |
|
|
Nitrile | # | # | ☆ | ☆ |
|
|
Nitro-cellulose | △ |
|
|
|
|
|
Phenolic | △ | △ |
| △ |
|
|
Polyamide | ☆ | △ |
|
|
|
|
Polyester | # | # |
|
| ☆ | △ |
Polyether | # |
|
|
| ☆ |
|
Polyolefin | # | △ |
|
| ☆ | ☆ |
Polysulfide | # | # | ☆ | ☆ |
|
|
Polyurethane | ☆ | # |
| ☆ |
|
|
Polyvinyl butyral | # |
|
|
|
|
|
PUD | △ | # |
|
|
|
|
Silicone |
|
|
|
| ☆ | △ |
SBR emulsion |
| # |
|
|
|
|
Styrene butadiene | # | # | ☆ | ☆ |
|
|
Urea-formaldehyde | △ | △ |
|
|
|
|
Vinyl | △ |
|
|
|
|
|
☆=Generally Effective △=Alternate #=Only effective with specific silane grades
Functional groups must be evaluated by customers for compatibility with listed resins. This should be used as a guide only.
Application: Benefits
Adhesives: Moisture- initiated crosslinking of resin, improve wet adhesion, Primerless adhesion to many materials, improved chemical resistance weatherablity and durability
Coatings & Inks: Moisture- initiated crosslinking of resin, improve wet adhesion, Chemical and corrosion resistance, weatherability, pigment dispersion and scrub resistance
Fiber Reinforced: Coupling of resins with fibers for improved resiliency of insulation
Composites and: batts, better wet strength retention and electrical properties of
Glass Insulation: FRP composites, and improved fiber strand integrity, protection And handling
Filler Treatment: Improved coupling of resins with fillers, better filler dispersion and Processing ease in thermoset and thermoplastic resins
Polymer Modification: Moisture-cure crosslinking for improved environmental and Chemical resistance
Rubber and Elastomers: Coupling of resins with mineral for improved composite strength Toughness, abrasion resistance, rolling resistance, wet Electrical Properties and rheology control, fewer mixing steps and better Silica dispersion
Sealants: Moisture-initiated crosslinking of resins, improved adhesion, Chemical resistance, filler dispersion and weatherability
Thermoplastics: Moisture-curable crosslinked polyethylene for wire & cables and Polyethylene crosslinked (PEX) pipes, mineral and pigment Treatment for dispersibility and coupling of resins with fillers in High performance thermoplastics
Tires: Coupling silica in tire compounds to improve the rolling resistance Traction and wear. New generation silanes may facilitate higher-efficiency tire manufacturing while enhancing tire performance
Please contact Silfluo for more info.